Two birds with one stone: dual grain-boundary and interface passivation enables >22% efficient inverted methylammonium-free perovskite solar cells

Author:

Gharibzadeh Saba12ORCID,Fassl Paul12ORCID,Hossain Ihteaz M.12,Rohrbeck Pascal3ORCID,Frericks Markus45ORCID,Schmidt Moritz126ORCID,Duong The7ORCID,Khan Motiur Rahman1ORCID,Abzieher Tobias1,Nejand Bahram Abdollahi12ORCID,Schackmar Fabian12,Almora Osbel8ORCID,Feeney Thomas1,Singh Roja12ORCID,Fuchs Dirk9,Lemmer Uli1,Hofmann Jan P.45ORCID,Weber Stefan A. L.3,Paetzold Ulrich W.12ORCID

Affiliation:

1. Light Technology Institute, Karlsruhe Institute of Technology, Engesserstrasse 13, 76131 Karlsruhe, Germany

2. Institute of Microstructure Technology, Karlsruhe Institute of Technology, Hermann-von Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

3. Max Planck Institute for polymer research, department physics at interfaces, Ackermannweg 10, 55128 Mainz, Germany

4. Technical University of Darmstadt, Department of Materials and Earth Sciences, Surface Science Laboratory, Otto-Berndt-Strasse 3, 64287 Darmstadt, Germany

5. InnovationLab GmbH, Speyerer Strasse 4, 69115 Heidelberg, Germany

6. Center for Nanophotonics, AMOLF, 1098 XG Amsterdam, The Netherlands

7. School of Engineering, The Australian National University, Canberra, 2601, Australia

8. Institute of Advanced Materials, Universitat Jaume I, 12006 Castelló, Spain

9. Insitute for Quantum Materials and Technologies, Karlsruhe Institute of Technology, Herrmann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

We present a dual passivation approach for p–i–n perovskite solar cells using phenethylammonium chloride that simultaneously passivates defects at the grain boundaries and the perovskite/C60 interface, thus substantially enhancing both VOC and FF.

Funder

Bundesministerium für Wirtschaft und Energie

H2020 Industrial Leadership

Baden-Württemberg Stiftung

H2020 Energy

Helmholtz-Gemeinschaft

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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