Mechanochemical palladium-catalyzed C(sp2)–H homocoupling of N-arylcarbamates: synthesis of 2,2′-biaryldiamines-Reference-Cited by-同舟云学术

Mechanochemical palladium-catalyzed C(sp2)–H homocoupling of N-arylcarbamates: synthesis of 2,2′-biaryldiamines

Published:2018 Issue:13 Volume:5 Page:2103-2107
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Weng Yiyi¹²³⁴^ORCID,Lan Tianwen⁵²³⁴^ORCID,Sun Chen¹²³⁴,Yang Ting¹²³⁴,Su Weike¹²³⁴⁵,Xie Yuanyuan¹²³⁴^ORCID

Affiliation:

1. College of Pharmaceutical Sciences

2. Zhejiang University of Technology

3. Hangzhou 310014

4. P.R. China

5. Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals

Abstract

The palladium-catalyzed dehydrogenative C(sp²)–H homocoupling of N-arylcarbamates under high-speed ball-milling conditions has been achieved using weakly coordinating directing groups, providing access to a variety of 2,2′-biaryldicarbamates.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00420J

Reference49 articles.

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3. Mechanism of Asymmetric Hydrogenation of Aromatic Ketones Catalyzed by a Combined System of Ru(π-CH2C(CH3)CH2)2(cod) and the Chiral sp2N/sp3NH Hybrid Linear N4 Ligand Ph-BINAN-H-Py

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