Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir–η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion-Reference-Cited by-同舟云学术

Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir–η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion

Published:2016 Issue:3 Volume:7 Page:2335-2341
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Liu Leo¹²³⁴⁵,Ruiz David A.¹²³⁴⁵,Dahcheh Fatme¹²³⁴⁵,Bertrand Guy¹²³⁴⁵,Suter Riccardo⁶⁷⁸⁹,Tondreau Aaron M.⁶⁷⁸⁹,Grützmacher Hansjörg⁶⁷⁸⁹

Affiliation:

1. UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555)

2. Department of Chemistry and Biochemistry

3. University of California San Diego

4. La Jolla

5. USA

6. Department of Chemistry and Applied Biosciences

7. ETH Zürich

8. 8093 Zürich

9. Switzerland

Abstract

Sodium phosphaethynolate reacts with [MCl(PDI)] (M = Co, Ir; PDI = pyridinediimine) to give metallaphosphaketenes, which in the case of iridium rearranges into a dimetalladiphosphene.

Funder

Division of Chemistry

China Scholarship Council

U.S. Department of Education

Swiss National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04504E

Reference65 articles.

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5. Coulomb repulsion versus cycloaddition: formation of anionic four-membered rings from sodium phosphaethynolate, Na(OCP)

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