Biomimetic-inspired synthesis of sporochartines through Diels–Alder reaction between enantiopure (−)-sporothriolide and (+)-trienylfuranol A-Reference-Cited by-同舟云学术

Biomimetic-inspired synthesis of sporochartines through Diels–Alder reaction between enantiopure (−)-sporothriolide and (+)-trienylfuranol A

Published:2023 Issue:16 Volume:10 Page:4111-4121
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Arcile Guillaume¹,Massard Théo²,van Elslande Elsa²,Ouazzani Jamal¹,Betzer Jean-François²^ORCID

Affiliation:

1. Institut de Chimie des Substances Naturelles (ICSN), CNRS UPR 2301, Université Paris-Saclay, Department of Natural Products and Medicinal Chemistry, Gif-sur-Yvette, France

2. Institut de Chimie des Substances Naturelles (ICSN), CNRS UPR 2301, Université Paris-Saclay, Department of Organic Synthesis and Catalytic Methods, Gif-sur-Yvette, France

Abstract

A reaction between synthesized enantiopure (+)-trienylfuranol A and cultivated (−)-sporothriolide allowed us to confirm that the spiranic backbones of sporochartines are formed by a [4 + 2] cycloaddition reaction.

Funder

Centre National de la Recherche Scientifique

Université Paris-Saclay

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00971H

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