The crystal and defect structures of polar KBiNb2O7

Author:

Mallick Subhadip1,Zhang Weiguo2,Batuk Maria3ORCID,Gibbs Alexandra S.4,Hadermann Joke3ORCID,Halasyamani P. Shiv2ORCID,Hayward Michael A.1ORCID

Affiliation:

1. Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, OX1 3QR, UK

2. Department of Chemistry, University of Houston, 112 Fleming Building, Houston, Texas 77204-5003, USA

3. EMAT, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium

4. ISIS Facility, Rutherford Appleton Laboratory, Chilton, Oxon OX11 0QX, UK

Abstract

KBiNb2O7 adopts a polar, layered, (0, ½, z) stacked crystal structure, which exhibits many ‘axis switch’ stacking faults.

Funder

Somerville College, University of Oxford

Diamond Light Source

National Science Foundation

Science and Technology Facilities Council

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference36 articles.

1. M. E.Lines and A. M.Glass , Principles and Applications of Ferroelectrics and Related Materials , Oxford University Press , Oxford , 1991

2. F. J.Nye , Physical Properties of Crystals , Oxford University Press , Oxford, UK , 1957

3. Origin of ferroelectricity in perovskite oxides

4. Out-of-Center Distortions around Octahedrally Coordinated d0 Transition Metals

5. Structures for d0 ML6 and ML5 complexes

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