Reversible addition of tin(<scp>ii</scp>) amides to nitriles-Reference-Cited by-同舟云学术

Reversible addition of tin(ii) amides to nitriles

Published:2022 Issue:5 Volume:51 Page:1879-1887
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chlupatý Tomáš¹^ORCID,Brichová Kristýna¹,Samsonov Maksim A.¹,Růžičková Zdeňka¹,Růžička Aleš¹^ORCID

Affiliation:

1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ-532 10, Pardubice, Czech Republic

Abstract

Amidotin(ii) benzamidinates were prepared via addition of Sn[N(SiMe3)2]2 to mono-, di- and trinitriles. A reversible addition of [PhC(NSiMe3)2]SnN(SiMe3)2 with an excess of benzonitrile to its homoleptic [PhC(NSiMe3)2]2Sn was studied by NMR and DFT.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04060J

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