Control of nuclearity in heterometallic CuII–MnIIcomplexes derived from asymmetric Schiff bases: structures and magnetic properties
Author:
Affiliation:
1. Department of Chemistry
2. University College of Science
3. University of Calcutta
4. Kolkata 700009
5. India
6. Sri Ramkrishna Sarada Vidyamahapitha
7. Kamarpukur
8. School of Chemistry
9. The University of Reading
10. Reading RG6 6AD
11. U.K
Abstract
Among three asymmetric Schiff bases used for the synthesis of heterometallic CuII–MnIIcomplexes, the one with N2O2donor atoms yielded a tetranuclear and a trinuclear complex whereas two N2O3donor ligands produced solely dinuclear complexes. The results of magnetic measurements have been justified by DFT study.
Funder
Council of Scientific and Industrial Research
Department of Science and Technology, Ministry of Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04766E
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