Control of nuclearity in heterometallic CuII–MnIIcomplexes derived from asymmetric Schiff bases: structures and magnetic properties

Author:

Mahapatra Prithwish12345,Giri Sanjib1675ORCID,Drew Michael G. B.891011,Ghosh Ashutosh12345ORCID

Affiliation:

1. Department of Chemistry

2. University College of Science

3. University of Calcutta

4. Kolkata 700009

5. India

6. Sri Ramkrishna Sarada Vidyamahapitha

7. Kamarpukur

8. School of Chemistry

9. The University of Reading

10. Reading RG6 6AD

11. U.K

Abstract

Among three asymmetric Schiff bases used for the synthesis of heterometallic CuII–MnIIcomplexes, the one with N2O2donor atoms yielded a tetranuclear and a trinuclear complex whereas two N2O3donor ligands produced solely dinuclear complexes. The results of magnetic measurements have been justified by DFT study.

Funder

Council of Scientific and Industrial Research

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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