Organocatalysis and catalyst aggregation: a study using the asymmetric synthesis of benzofuranones as a test reaction-Reference-Cited by-同舟云学术

Organocatalysis and catalyst aggregation: a study using the asymmetric synthesis of benzofuranones as a test reaction

Published:2018 Issue:38 Volume:16 Page:7041-7049
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Salvio Riccardo¹²³⁴⁵^ORCID,Massaro Luca¹²³⁴⁵^ORCID,Puglisi Antonio¹²³⁴⁵^ORCID,Angelini Lucrezia¹²³⁴⁵^ORCID,Antenucci Achille¹²³⁴⁵^ORCID,Placidi Simone¹²³⁴⁵^ORCID,Sciubba Fabio¹²³⁴⁵^ORCID,Galantini Luciano¹²³⁴⁵^ORCID,Bella Marco¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. “Sapienza” University of Rome

3. P.le Aldo Moro 5

4. 00185 Roma

5. Italy

Abstract

An aggregation phenomenon involving Cinchona alkaloid derivatives deeply affects the performance of the catalyst in an organocatalytic process – a mechanistic study.

Funder

Sapienza Università di Roma

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB01772G

Reference33 articles.

1. Cinchona Alkaloids in Synthesis and Catalysis: Ligands, Immobilization and Organocatalysis , ed. C. E. Song , Wiley-VCH Verlag GmbH & Co. KGaA , 2009

2. Organocatalysis—after the gold rush

3. Asymmetric Organocatalysis , ed. B. List and K. Maruoka , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim , Workbench edn, 2013 , vol. 2

4. A Highly Reactive and Enantioselective Bifunctional Organocatalyst for the Methanolytic Desymmetrization of Cyclic Anhydrides: Prevention of Catalyst Aggregation

5. Bifunctional organocatalyst for methanolytic desymmetrization of cyclic anhydrides: increasing enantioselectivity by catalyst dilution

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