Solution structural characterization of an array of nanoscale aqueous inorganic Ga13−xInx (0 ≤ x ≤ 6) clusters by 1H-NMR and QM computations-Reference-Cited by-同舟云学术

Solution structural characterization of an array of nanoscale aqueous inorganic Ga13−xInx (0 ≤ x ≤ 6) clusters by 1H-NMR and QM computations

Published:2015 Issue:7 Volume:6 Page:4071-4085
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Oliveri Anna F.¹²³⁴,Wills Lindsay A.⁵⁶⁷⁴,Hazlett Caitlyn R.¹²³⁴,Carnes Matthew E.¹²³⁴,Chang I-Ya⁵⁶⁷⁴,Ha-Yeon Cheong Paul⁵⁶⁷⁴,Johnson Darren W.¹²³⁴

Affiliation:

1. Department of Chemistry & Biochemistry and Materials Science Institute

2. University of Oregon

3. Eugene

4. USA

5. Department of Chemistry

6. Oregon State University

7. Corvallis

Abstract

Complete structural determination by ¹H NMR spectroscopy and QM computations reveals a series of heterometallic Ga_13−xIn_x(μ₃-OH)₆(μ₂-OH)₁₈(H₂O)₂₄](NO₃)₁₅ clusters persist in solution and can exist as an isomeric mixture.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC00776C

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