Cooperative CO<sub>2</sub> adsorption mechanism in a perfluorinated Ce<sup>IV</sup>-based metal organic framework-Reference-Cited by-同舟云学术

Cooperative CO₂ adsorption mechanism in a perfluorinated Ce^IV-based metal organic framework

Published:2023 Issue:11 Volume:11 Page:5568-5583
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Cavallo Margherita¹,Atzori Cesare¹²^ORCID,Signorile Matteo¹^ORCID,Costantino Ferdinando³^ORCID,Venturi Diletta Morelli³,Koutsianos Athanasios⁴,Lomachenko Kirill A.²^ORCID,Calucci Lucia⁵⁶^ORCID,Martini Francesca⁶⁷^ORCID,Giovanelli Andrea⁷^ORCID,Geppi Marco⁶⁷^ORCID,Crocellà Valentina¹^ORCID,Taddei Marco⁶⁷⁸^ORCID

Affiliation:

1. Dipartimento di Chimica, Centro di Riferimento NIS e INSTM, Università di Torino, Via G. Quarello 15, I-10135 and Via P. Giuria 7, I-10125 Torino, Italy

2. European Synchrotron Radiation Facility, 71 Avenue des Martyrs, CS 40220, 38043 Grenoble Cedex 9, France

3. Dipartimento di Chimica, Biologia e Biotecnologie, Unità di Ricerca INSTM, Università di Perugia, Via Elce di Sotto 8, 06123 Perugia, Italy

4. Centre for Research & Technology Hellas/Chemical Process and Energy Resources Institute, 6th km. Charilaou-Thermis, 57001, Greece

5. Istituto di Chimica dei Composti Organo Metallici, Unità di Ricerca INSTM, Consiglio Nazionale delle Ricerche, Via Giuseppe Moruzzi 1, 56124 Pisa, Italy

6. Centro per l’Integrazione della Strumentazione Scientifica dell’Università di Pisa (CISUP), 56126, Pisa, Italy

7. Dipartimento di Chimica e Chimica Industriale, Unità di Ricerca INSTM, Università di Pisa, Via Giuseppe Moruzzi 13, 56124 Pisa, Italy

8. Energy Safety Research Institute, Swansea University, Fabian Way, Swansea, SA1 8EN, UK

Abstract

The peculiar mechanism of cooperative CO2 adsorption in a perfluorinated CeIV-based metal–organic framework with MIL-140 topology is disclosed using a combination of experimental and computational methods.

Funder

Università di Pisa

Horizon 2020 Framework Programme

Marie Curie

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D2TA09746J

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1. Engineering metal–organic frameworks for adsorption-based gas separations: from process to atomic scale