X-ray absorption spectroscopy insights on the structure anisotropy and charge transfer in Chevrel Phase chalcogenides-Reference-Cited by-同舟云学术

X-ray absorption spectroscopy insights on the structure anisotropy and charge transfer in Chevrel Phase chalcogenides

Published:2022 Issue:28 Volume:24 Page:17289-17294
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Hyler Forrest P.¹^ORCID,Wuille Bille Brian A.¹^ORCID,Ortíz-Rodríguez Jessica C.¹^ORCID,Sanz-Matias Ana²³^ORCID,Roychoudhury Subhayan²,Perryman Joseph T.⁴^ORCID,Patridge Christopher J.⁵^ORCID,Singstock Nicholas R.⁶^ORCID,Musgrave Charles B.⁶,Prendergast David²^ORCID,Velázquez Jesús M.¹^ORCID

Affiliation:

1. Department of Chemistry, University of California, One Shields Avenue, Davis, California, 95616, USA

2. Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, USA

3. Joint Center for Energy Storage Research, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, USA

4. Department of Chemical Engineering, Stanford University, 443 Via Ortega, Stanford, California, 94305, USA

5. Department of Chemistry, D’Youville College, 320 Porter Avenue, Buffalo, New York, 14201, USA

6. Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80303, USA

Abstract

The electronic structure and local coordination of binary (Mo6T8, T = S, Se, Te) and ternary Chevrel Phases (MxMo6T8, M = transition metal) are investigated for a range of metal intercalant and chalcogen compositions through XANES and EXAFS analyses.

Funder

Research Corporation for Science Advancement

Office of Science

Lawrence Berkeley National Laboratory

Brookhaven National Laboratory

National Science Foundation

University of California, Davis

National Energy Research Scientific Computing Center

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy