Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C–H bond functionalization
Author:
Affiliation:
1. C. L. Emerson Center for Scientific Computation
2. Emory University
3. Atlanta, USA
Abstract
The C–H functionalization strategies, complexity in Pd-catalyzed chemical transformations, unprecedented Pd-clustering, base (Cs-halide) and weakly coordinated amino acid ligand effects.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CS/C3CS60447K
Reference252 articles.
1. Activation of C−H Bonds by Metal Complexes
2. Catalytic Functionalization of Arenes and Alkanes via C−H Bond Activation
3. Ru-, Rh-, and Pd-Catalyzed C−C Bond Formation Involving C−H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic Aspects
4. C−C, C−O, C−N Bond Formation on sp2 Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant Agents
5. Direct transition metal-catalyzed functionalization of heteroaromatic compounds
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