Covalent lanthanide(iii) macrocyclic complexes: the bonding nature and optical properties of a promising single antenna molecule
Author:
Affiliation:
1. Relativistic Molecular Physics (ReMoPh) Group
2. Ph.D. Program in Molecular Physical Chemistry
3. Universidad Andrés Bello
4. Santiago 8370146, Chile
Abstract
The present work is focused on the elucidation of the electronic structure, bonding and optical properties of a series of coordination compounds of type [LnIIIHAM]3+, where “LnIII” are the trivalent lanthanide ions: La3+, Ce3+, Eu3+ and Lu3+, while “HAM” is the neutral six-nitrogen macrocyclic ligand [C22N6H26].
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP03882G
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