CuH-catalysed hydroamination of arylalkynes with hydroxylamine esters – a computational scrutiny of rival mechanistic pathways-Reference-Cited by-同舟云学术

CuH-catalysed hydroamination of arylalkynes with hydroxylamine esters – a computational scrutiny of rival mechanistic pathways

Published:2017 Issue:6 Volume:8 Page:4410-4423
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tobisch Sven¹²³

Affiliation:

1. University of St Andrews

2. School of Chemistry

3. UK KY16 9ST

Abstract

An in-depth computational mechanistic probe of the CuH-mediated hydroamination of internal arylalkynes with amine electrophile and hydrosilane defines the most accessible pathways for rival avenues of direct and reductive hydroamination, from which a general understanding of the factors controlling formal hydroamination catalysis emerges.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC01107E

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