Nickel-catalyzed aryl trifluoromethyl sulfide synthesis: a DFT study
Author:
Affiliation:
1. Departament de Química Inorgànica i Orgànica
2. Secció de Química Inorgànica and Institut de Química Teòrica i Computacional (IQTC-UB)
3. Universitat de Barcelona
4. 08028 Barcelona
5. Spain
Abstract
A Ni(i)/Ni(iii) catalytic cycle allows aryl trifluoromethyl sulfides to be obtained at room temperature from [NMe4][SCF3] and aryl halides.
Funder
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CY/C9CY01365B
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3. Formation of CSCF3Bonds through Direct Trifluoromethylthiolation
4. Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions
5. Direct C-H trifluoromethylthiolation of (hetero)arenes: A review
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