Solvation rules: aromatic interactions outcompete cation–π interactions in synthetic host–guest complexes in water-Reference-Cited by-同舟云学术

Solvation rules: aromatic interactions outcompete cation–π interactions in synthetic host–guest complexes in water

Published:2023 Issue:95 Volume:59 Page:14146-14148
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Tobajas-Curiel Gloria¹^ORCID,Sun Qingqing²³,Sanders Jeremy K. M.¹^ORCID,Ballester Pablo²⁴^ORCID,Hunter Christopher A.¹^ORCID

Affiliation:

1. Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK

2. Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology (BIST), Av. Països Catalans, 16, 43007, Tarragona, Spain

3. Yangzhou University, School of Chemistry and Chemical Engineering, Yangzhou, Jiangsu 225002, China

4. ICREA, Passeig Lluís Companys 23, Barcelona 08010, Spain

Abstract

Chemical double mutant cycles were used to measure the interaction of a π-box in a calix[4]pyrrole receptor with a cationic N-methyl pyridinium group and with neutral isosteric analogues in water.

Funder

Agència de Gestió d'Ajuts Universitaris i de Recerca

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC04399A

Reference23 articles.

1. Molecular Recognition in Water Using Macrocyclic Synthetic Receptors

2. Molecular Recognition Mediated by Hydrogen Bonding in Aqueous Media

3. The Cation−π Interaction

4. The Cation−π Interaction

5. Aromatic Rings in Chemical and Biological Recognition: Energetics and Structures