Reactivity of the binuclear hydride [Fe2(CO)4(µ-H)(µ-CO)(µ-PPh2)(µ-Ph2PCH2PPh2)] to generate phosphido and hydroxide moieties at the diiron centre
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1993/DT/DT9930000143
Reference25 articles.
1. Synthesis and reactivity towards unsaturated organics of the diiron hydride complex [Fe2(CO)4(µ-CO)(µ-H)-(µ-PPh2)(µ-Ph2PCH2PPh2)]
2. Hydrido heterobimetallic bis(diphenylphosphino)methane-bridged ruthenium-rhodium complexes. Activation of a phosphorus-carbon bond of bis(diphenylphosphino)methane to give a heterobimetallic ruthenium-rhodium complex containing a trans-hydridophenylruthenium moiety. X-ray crystal structure of RuRhH(C6H5)(C8H12)[C6H5PCH2P(C6H5)2][(C6H5)2PCH2P(C6H5)2].cntdot.0.5C6H5CH3
3. Transformation of the bis(diphenylphosphino)methane ligand on the triruthenium nonacarbonyl framework. Synthesis and characterization of the ruthenium complexes Ru3(CO)9(.mu.3-.eta.3-P(C6H5)CH2P(C6H5)(C6H4)), Ru3(CO)9(.mu.-H)(.mu.3-.eta.2-P(C6H5)CH2P(C6H5)2), and Ru3(CO)10(.mu.-.eta.2-P(C6H5)CH2P(C6H5)(C6H4))
4. Aspects of the chemistry of substituted ruthenium clusters involving bis(diphenylphosphino)- or bis(diphenylarsino)methane as bridging ligands. Reactivity toward hydrogen and potential applications in catalysis. Crystal and molecular structure of (.mu.-H)2Ru3(CO)6(.mu.-P(C6H5)CH2P(C6H5)2)2 and (.mu.-H)2Ru3(CO)6(.mu.-As(C6H5)CH2As(C6H5)2)2
5. Phosphorus–carbon bond cleavage at a di-iron centre. Conversion of µ-R2PCH2PR2to µ-R2PCH2and µ-PR2: crystal structures of [Fe2(CO)4(µ-Ph2PCH2)(µ-PPh2)(µ-Me2PCH2PMe2)] and [Fe2(CO)6{µ-PhPCH(Me)P(Ph)(C6H4-O)}]
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4. Contrasting Protonation Behavior of Diphosphido vs Dithiolato Diiron(I) Carbonyl Complexes;Organometallics;2012-12-27
5. Diphosphine Mobility at a Binuclear Metal Center: A Concerted Double Trigonal-Twist in Bis(dithiolate) Complexes [M2(CO)4(μ-dppm){μ-S(CH2)nS}] (M = Fe, Ru; n = 2, 3);Organometallics;2010-11-16
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