The reaction of bromo- and iodo-phosphoranes with unactivated coarse grain manganese metal powder to yield [MnI2(phosphine)2] and [{MnX2(phosphine)}n](X = Br or I) by insertion of Mn into the P–X bond. The crystal structure of [MnI2(PPh3)2]-Reference-Cited by-同舟云学术

The reaction of bromo- and iodo-phosphoranes with unactivated coarse grain manganese metal powder to yield [MnI2(phosphine)2] and [{MnX2(phosphine)}n](X = Br or I) by insertion of Mn into the P–X bond. The crystal structure of [MnI2(PPh3)2]

Published:1993 Issue:3 Volume: Page:371-375
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Godfrey Stephen M.,McAuliffe Charles A.,Pritchard Robin G.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1993/DT/DT9930000371

Reference23 articles.

1. The reaction of coarse-grain metal powders with phosphoranes: a facile activation of metallic reagents and a novel route to metal–phosphine complexes. The X-ray crystal structures of Mnl2(PPhMe2) and FeBr3(PPhMe2)2

2. The Reaction of Unactivated Cobalt Powder with Iodophosphoranes. The Synthesis of [Co(PMe3)2I3] and the Isolation of the ?Frozen Transition-State? Complex [(nBu3PI)2(?-I)] [(nBu3PI)(?-I)CoI3]

3. The X-ray crystal structure of [Zn(PEt3)I2]2, the first 1:1 zinc(II) complex of a tertiary phosphine of low steric requirements, prepared by the reaction of unactivated zinc metal with diiodotriethylphosphorane

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