Correlating the chemical structure and charge transport ability of dibenzofulvene-based hole transporting materials for stable perovskite solar cells

Author:

Leoncini M.12,Capodilupo A.-L.1ORCID,Altamura D.3ORCID,Giannini C.3,Accorsi G.1,Fabiano E.45,Rizzo A.1ORCID,Gigli G.12,Gambino S.1ORCID

Affiliation:

1. CNR NANOTEC – Istituto di Nanotecnologia, c/o Campus Ecotekne, Via Monteroni, 73100 Lecce, Italy

2. Dipartimento di Matematica e Fisica “E. De Giorgi”, Università del Salento, c/o Campus Ecotekne, via Arnesano, 73100 Lecce, Italy

3. CNR IC – Istituto di Cristallografia, via Amendola 122/O, 70126, Bari, Italy

4. CNR IMM – Istituto di Microelettronica e Microsistemi, c/o Campus Ecotekne, Via Monteroni, 73100, Lecce, Italy

5. IIT – Istituto Italiano di Tecnologia, Centre for Biomolecular Nanotechnologies, Via Barsanti 14, Lecce 73010, Italy

Abstract

By modifying the size and shape of the molecules, we managed to tune the hole mobility of our HTMs up to three orders of magnitude. Our best HTM led to a solar cell lifetime that is tripled compared to that based on spiro-OMeTAD.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Regione Puglia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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