Reactivity and rotational spectra: the old concept of substitution effects-Reference-Cited by-同舟云学术

Reactivity and rotational spectra: the old concept of substitution effects

Published:2020 Issue:20 Volume:22 Page:11490-11497
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Herbers Sven¹²³⁴^ORCID,Buschmann Philipp¹²³⁴^ORCID,Wang Juan¹²³⁴⁵,Lengsfeld Kevin Gregor¹²³⁴,Nair K. P. Rajappan¹²³⁴⁶,Grabow Jens-Uwe¹²³⁴^ORCID

Affiliation:

1. Institut für Physikalische Chemie und Elektrochemie

2. Leibniz Universität Hannover

3. 30167 Hannover

4. Germany

5. Department of Chemistry

6. Department of Atomic and Molecular Physics

Abstract

The internal rotation of methyl groups and nuclear quadrupole moments of the halogens Cl, Br, I ino-halotoluenes result in complex spectral fine and hyperfine structures in rotational spectra which can be related to qualitative concepts in chemistry.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP01145B

Reference48 articles.

1. The Robinson-Ingold controversy: Precedence in the electronic theory of organic reactions

2. Aromatic Nitration with Potassium Nitrate or Nitric Acid and Boron Trifluoride Monohydrate

3. New measurements and global analysis of rotational spectra of Cl-, Br-, and I-benzene: Spectroscopic constants and electric dipole moments