The copper(i) metal azolate framework showing unusual coordination mode for the 1,2,4-triazole derivative and photocatalytic activity
Author:
Affiliation:
1. Institute of Functional Material Chemistry
2. Key Laboratory of Polyoxometalate Science of Ministry of Education
3. Northeast Normal University
4. Changchun
5. People's Republic of China
Abstract
A novel photocatalyst containing a tetranuclear Cu4 cluster constructed by six 1,2,4-triazole units was reported where two of the six 1,2,4-triazole units show unusual bridging “crevice” coordination mode with their 1- and 2-positioned sp2 N-atoms as symmetrically bridging centers.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03933E
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