The copper(i) metal azolate framework showing unusual coordination mode for the 1,2,4-triazole derivative and photocatalytic activity

Author:

Song Bai-Qiao12345,Qin Chao12345,Zhang Yu-Teng12345,Wu Xue-Song12345,Shao Kui-Zhan12345,Su Zhong-Min12345

Affiliation:

1. Institute of Functional Material Chemistry

2. Key Laboratory of Polyoxometalate Science of Ministry of Education

3. Northeast Normal University

4. Changchun

5. People's Republic of China

Abstract

A novel photocatalyst containing a tetranuclear Cu4 cluster constructed by six 1,2,4-triazole units was reported where two of the six 1,2,4-triazole units show unusual bridging “crevice” coordination mode with their 1- and 2-positioned sp2 N-atoms as symmetrically bridging centers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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