Elucidating the activity, mechanism and application of selective electrosynthesis of ammonia from nitrate on cobalt phosphide-Reference-Cited by-同舟云学术

Elucidating the activity, mechanism and application of selective electrosynthesis of ammonia from nitrate on cobalt phosphide

Published:2022 Issue: Volume: Page:
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Ye Shenghua¹²,Chen Zhida¹,Zhang Guikai³,Chen Wenda¹,Peng Chao⁴,Yang Xiuyuan⁴,Zheng Lirong³^ORCID,Li Yongliang¹^ORCID,Ren Xiangzhong¹,Cao Huiqun¹,Xue Dongfeng⁴^ORCID,Qiu Jieshan⁵,Zhang Qianling¹^ORCID,Liu Jianhong¹²

Affiliation:

1. Graphene Composite Research Center, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, P. R. China

2. Shenzhen Eigen-Equation Graphene Technology Co. Ltd., Shenzhen 518000, P. R. China

3. Institute of High Energy Physics Chinese Academy of Sciences, Beijing 100049, P. R. China

4. Multiscale Crystal Materials Research Center, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China

5. College of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, China

Abstract

Cobalt phosphide is an effective electrocatalyst for NO3− electroreduction into NH3. Phosphorus is crucial for stabilizing the active phase and optimizing energy barriers, and Co 4p orbitals directly participate in the nitrate reduction.

Funder

National Key Research and Development Program of China

Shenzhen Technical Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/EE/D1EE03097C

Reference37 articles.

1. Nitrogen Cycle Electrocatalysis

2. Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water