A vibrational circular dichroism (VCD) methodology for the measurement of enantiomeric excess in chiral compounds in the solid phase and for the complementary use of NMR and VCD techniques in solution: the camphor case-Reference-Cited by-同舟云学术

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A vibrational circular dichroism (VCD) methodology for the measurement of enantiomeric excess in chiral compounds in the solid phase and for the complementary use of NMR and VCD techniques in solution: the camphor case

Published:2018 Issue:6 Volume:143 Page:1406-1416
ISSN:0003-2654
Container-title:The Analyst
language:en
Short-container-title:Analyst

Author:

Quesada-Moreno María Mar¹²³⁴⁵^ORCID,Virgili Albert⁶⁷⁸⁹,Monteagudo Eva⁶⁷⁸⁹^ORCID,Claramunt Rosa M.¹⁰¹¹¹²¹³⁹^ORCID,Avilés-Moreno Juan Ramón¹⁴¹⁵³¹⁶¹⁷^ORCID,López-González Juan Jesús¹²³⁴⁵^ORCID,Alkorta Ibon¹⁸¹⁹²⁰²¹⁹^ORCID,Elguero José¹⁸¹⁹²⁰²¹⁹^ORCID

Affiliation:

1. Grupo de Investigación Química Física Teórica y Experimental (FQM-173)

2. Departamento de Química Física y Analítica

3. Facultad de Ciencias Experimentales

4. Universidad de Jaén

5. E-23071 Jaén

6. Servei de Ressonància Magnètica Nuclear and Departament de Química

7. Universitat Autònoma de Barcelona

8. 08193 Bellaterra

9. Spain

10. Departamento de Química Orgánica y Bio-Orgánica

11. Facultad de Ciencias

12. Universidad Nacional de Educación a Distancia

13. E-28040 Madrid

14. Departamento de Sistemas Físicos

15. Químicos y Naturales

16. Universidad Pablo de Olavide

17. E-41013 Sevilla

18. Instituto de Química Médica

19. Centro de Química Orgánica “Lora-Tamayo”

20. CSIC

21. E-28006 Madrid

Abstract

For the first time, it is shown that VCD spectroscopy can be used to determine the % ee in chiral solid samples.

Funder

Ministerio de Economía y Competitividad

Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía

Consejería de Educación, Juventud y Deporte, Comunidad de Madrid

Universidad de Jaén

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrochemistry,Spectroscopy,Environmental Chemistry,Biochemistry,Analytical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/AN/C7AN01855J

Reference74 articles.

1. J. Jacques , A.Collet and S. H.Wilen , Enantiomers, Racemates, and Resolutions , Krieger Publishing Co , Malabar, Florida , 1994

2. On the validity of Wallach's rule: on the density and stability of racemic crystals compared with their chiral counterparts

3. Solution-Phase Racemization in the Presence of an Enantiopure Solid Phase

4. Racemizable systems crystallizing as conglomerate and spontaneous symmetry breaking

5. Advances in Organic Crystal Chemistry. Comprehensive reviews , ed. R. Tamura and M. Miyata , Springer , Tokyo , 2015

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4. Differentiation of solvatomorphs of active pharmaceutical ingredients (API) by solid-state vibrational circular dichroism (VCD);Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy;2024-04

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