The statistical probability factor in triplet mediated photon upconversion: a case study with perylene

Author:

Naimovičius Lukas12ORCID,Radiunas Edvinas2ORCID,Dapkevičius Manvydas2,Bharmoria Pankaj1ORCID,Moth-Poulsen Kasper1345ORCID,Kazlauskas Karolis2ORCID

Affiliation:

1. Institute of Materials Science of Barcelona, ICMAB-CSIC, Bellaterra, Barcelona, 08193, Spain

2. Institute of Photonics and Nanotechnology, Vilnius University, Saulėtekio Av. 3, LT-10257 Vilnius, Lithuania

3. Catalan Institution for Research & Advanced Studies, ICREA, Pg. Lluís Companys 23, Barcelona, Spain

4. Department of Chemical Engineering, Universitat Politècnica de Catalunya, EEBE, Eduard Maristany 10–14, 08019 Barcelona, Spain

5. Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Kemivagen 4, Gothenburg 412 96, Sweden

Abstract

Experimentally determined statistical probability factor in TTA-mediated photon upconversion for perylene is ∼18%, predominantly dictated by the energy-gap law. This limits the maximum TTA-UC quantum yield to 9.0 % (out of 50%) for this annihilator.

Funder

Energimyndigheten

H2020 European Research Council

Göran Gustafssons Stiftelse för Naturvetenskaplig och Medicinsk Forskning

Institució Catalana de Recerca i Estudis Avançats

HORIZON EUROPE Climate, Energy and Mobility

Vetenskapsrådet

Svenska Forskningsrådet Formas

'la Caixa' Foundation

Erasmus+

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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