Preservation of epoxy groups on surfaces in the covalent attachment of butadiene monoxide on Si(111)-(7×7): the effect of a vinyl substituent

Author:

Mao Wei12345,He Jing Hui678910,Gu Jia Qiang1234,Chen Wei123411,Wu Kai1213141516,Tok Eng Soon112174,Xu Guo Qin12345

Affiliation:

1. Department of Chemistry

2. National University of Singapore

3. Singapore 117543

4. Singapore

5. Singapore-Peking University Research Centre for a Sustainable Low-Carbon Future

6. College of Chemistry

7. Chemical Engineering and Materials Science

8. Collaborative Innovation Center of Suzhou Nano Science and Technology

9. Soochow University

10. Suzhou

11. Department of Physics

12. BNLMS

13. College of Chemistry and Molecular Engineering

14. Peking University

15. Beijing

16. China

17. Singapore 117542

Abstract

A vinyl substituent ensures that butadiene monoxide selectively binds to Si(111)-(7×7) through a [2+2]-like cycloaddition, maintaining an epoxy group in the cycloadduct.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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