Electrocatalytic water oxidation by heteroleptic ruthenium complexes of 2,6-bis(benzimidazolyl)pyridine Scaffold: a mechanistic investigation-Reference-Cited by-同舟云学术

Electrocatalytic water oxidation by heteroleptic ruthenium complexes of 2,6-bis(benzimidazolyl)pyridine Scaffold: a mechanistic investigation

Published:2023 Issue:22 Volume:52 Page:7590-7601
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Khan Sahanwaj¹,Sengupta Swaraj²,Khan Md. Adnan¹,Sk Md. Palashuddin³^ORCID,Naskar Subhendu¹^ORCID

Affiliation:

1. Department of Chemistry, Birla institute of Technology-Mesra, Ranchi, India

2. Department of Chemical Engineering, Birla institute of Technology-Mesra, Ranchi, India

3. Department of Chemistry, Aligarh Muslim University, Aligarh, India

Abstract

Electrocatalytic water oxidation by new monomeric ruthenium complexes has been proposed to take place by Water Nucleophilic Attack. A methyl substitution in the ligand backbone increases the efficiency, whereas a fluoro group decreases the rate.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00128H

Reference83 articles.

1. The art of splitting water

2. The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis

3. Artificial photosynthesis: biomimetic approaches to solar energy conversion and storage

4. Making Oxygen with Ruthenium Complexes

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