Trimerization and tetramerization of ethylene in continuous gas-phase reaction using a Cr-based supported liquid phase catalyst-Reference-Cited by-同舟云学术

Trimerization and tetramerization of ethylene in continuous gas-phase reaction using a Cr-based supported liquid phase catalyst

Published:2019 Issue:1 Volume:4 Page:131-140
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Müller Tobias¹²³⁴,Dixon John Thomas⁵⁶⁷,Haumann Marco¹²³⁴^ORCID,Wasserscheid Peter¹²³⁴

Affiliation:

1. Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)

2. Lehrstuhl für Chemische Reaktionstechnik (CRT)

3. 91058 Erlangen

4. Germany

5. Sasol South Africa (Pty) Ltd

6. Sasolburg

7. South Africa

Abstract

Selective tri- and tetramerization of ethylene in continuous operation was achieved by immobilization of the homogeneous chromium catalyst plus MAO co-catalyst in a thin film of high boiling hydrocarbons.

Funder

Sasol

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RE/C8RE00179K

Reference34 articles.

1. A soluble chromium-based catalyst for ethylene trimerization and polymerization

2. Ethylene Tetramerization: A New Route to Produce 1-Octene in Exceptionally High Selectivities

3. Olefin Oligomerization via Metallacycles: Dimerization, Trimerization, Tetramerization, and Beyond

4. A. Jess and P.Wasserscheid , Chemical Technology: An integral textbook , Wiley-VCH , Weinheim , 2013 , pp. 749 and 803

5. Role of MAO in Chromium-Catalyzed Ethylene Tri- and Tetramerization: A DFT Study

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Ethylene Oligomerization Catalyzed by Different Homogeneous or Heterogeneous Catalysts;Catalysts;2024-04-17

2. Ethylene trimerization using half‐sandwich titanium‐based catalysts supported on mesoporous silica modified with ionic liquids;Applied Organometallic Chemistry;2024-03-07

3. Asymmetric carbon-bridged diphosphine based chromium complexes for selective ethylene tri-/tetramerization with high thermal stability;Journal of Catalysis;2022-09

4. Preparation of Extremely Active Ethylene Tetramerization Catalyst [iPrN(PAr2)2−CrCl2]+[B(C6F5)4]– (Ar = −C6H4-p-SiR3);Catalysts;2021-09-18

5. Chromium(III) catalysts based on tridentate silicon-bridged tris(diphenylphosphine) ligands for selective ethylene tri-/tetramerization;Journal of Catalysis;2020-12