A new family of 1D, 2D and 3D frameworks aggregated from Ni5, Ni4 and Ni7 building units: synthesis, structure, and magnetism

Author:

Liu Ya-Hui12345,Lu Li-Ping12345,Zhu Miao-Li12345,Feng Si-Si12345,Su Feng12345

Affiliation:

1. Institute of Molecular Science

2. Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry

3. Shanxi University

4. Taiyuan

5. P. R. China

Abstract

Three polynuclear nickel(ii) complexes with 1D, 2D and 3D structures are controlled by carboxylate bridges of biphenyl-3,4′,5-tricarboxylic acid. Magnetic studies reveal that the polymers have ferromagnetic coupling features for 1 and 2 and an alternating magnetic chain behavior for 3.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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