Anionic polymerization of phenyl-substituted isoprene derivatives: polymerization behaviour and cyclization-enabled fluorescence-Reference-Cited by-同舟云学术

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Anionic polymerization of phenyl-substituted isoprene derivatives: polymerization behaviour and cyclization-enabled fluorescence

Published:2024 Issue:31 Volume:15 Page:3204-3213
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Rauschenbach Moritz¹,Stein Laura¹,Linden Gregor M.¹,Barent Ramona¹²,Heinze Katja¹^ORCID,Frey Holger¹^ORCID

Affiliation:

1. Department of Chemistry. Johannes Gutenberg University, Duesbergweg 10-14, 55128 Mainz, Germany

2. Max Planck Graduate Center, Forum Universitatis 2, 55122 Mainz, Germany

Abstract

1-Phenyl isoprene (1PhI) and 4-phenyl isoprene (4PhI) are shown to be suitable for living anionic polymerisation, with Mn of up to 48.8 kg mol−1 (Đ ≤ 1.13). Reactivity ratios for copolymerisation with styrene and isoprene are also determined.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D4PY00601A

Reference59 articles.

1. ‘Living’ Polymers

2. Advances in Living Anionic Polymerization: From Functional Monomers, Polymerization Systems, to Macromolecular Architectures

3. N.Hadjichristidis and A.Hirao , Anionic Polymerization , Springer , Tokio , 2013

4. Multiblock Polymers: Panacea or Pandora’s Box?

5. Quo Vadis Carbanionic Polymerization?

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