New complexity for aromatic ring agostic interactions

Author:

Sajjad M. Arif1234,Christensen Kirsten E.56789,Rees Nicholas H.56789,Schwerdtfeger Peter10234,Harrison John A.1234,Nielson Alastair J.1234ORCID

Affiliation:

1. Chemistry, Institute of Natural and Mathematical Sciences

2. Massey University Auckland

3. Auckland

4. New Zealand

5. Inorganic Chemistry Laboratory

6. Department of Chemistry

7. University of Oxford

8. Oxford

9. UK

10. Centre for Theoretical and Physics, The New Zealand Institute for Advanced Study

Abstract

Aromatic ring agostic interactions can be augmented by previously unrecognised CCπ to metal donation which has significant implication for ligand-assisted C–H bond functionalization.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference37 articles.

1. E. M. Beck and M. J.Gaunt, in Topics in Current Chemistry: C–H Activation, ed. J. Q.Yu and Z. J.Shi, Springer-Verlag, Berlin, Heidelberg, 2010, vol. 292, pp. 85–121

2. CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

3. Towards mild metal-catalyzed C–H bond activation

4. Intramolecular five-membered ring compounds and their applications

5. The Potential of Palladacycles:  More Than Just Precatalysts

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