Exploring the coordinative adaptation and molecular shapes of trinuclear CuII2MII (M = Zn/Cd) complexes derived from salen type Schiff bases: structural and theoretical studies-Reference-Cited by-同舟云学术

Exploring the coordinative adaptation and molecular shapes of trinuclear CuII2MII (M = Zn/Cd) complexes derived from salen type Schiff bases: structural and theoretical studies

Published:2016 Issue:13 Volume:45 Page:5730-5740
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hazari Alokesh¹²³⁴⁵,Das Lakshmi Kanta¹⁶⁷⁵,Bauzá Antonio⁸⁹¹⁰¹¹,Frontera Antonio⁸⁹¹⁰¹¹^ORCID,Ghosh Ashutosh¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. University College of Science

3. University of Calcutta

4. Kolkata-700 009

5. India

6. Government General Degree College Kharagpur-II

7. Madpur

8. Departament de Química

9. Universitat de les IllesBalears

10. 07122 Palma de Mallorca (Baleares)

11. Spain

Abstract

Structural analyses and DFT studies of three new hetero-metallic compounds established that a slight modification in the ligand system or changes in the central metal ion can stabilize interesting novel structures with thiocyanate ion.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04941E

Reference73 articles.

1. Chemistry of Pseudohalides, ed. A. M. Golub, H. Kohler and V. V. Skopenko, Elsevier, Amsterdam, 1986

2. Infrared spectra of complexes of the thiocyanate and related ions

3. An X-ray absorption spectroscopy investigation of the coordination environment of electrogenerated Ni(ii)-pseudohalide complexes arising from the anodic polarization of Ni electrodes in DMSO solutions of NCO−, NCS− and NCSe− ions

4. Ambidentate ligands, the schizophrenics of coordination chemistry

5. Molecular and crystal engineering of a new class of inorganic cadmium-thiocyanate polymers with host–guest complexes as organic spacers, controllers, and templates

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