Synthesis, structure, and physical properties of new rare earth ferrocenoylacetonates

Author:

Koroteev Pavel S.1234,Dobrokhotova Zhanna V.1234,Ilyukhin Andrey B.1234,Efimov Nikolay N.1234,Rouzières Mathieu56789,Kiskin Mikhail A.1234,Clérac Rodolphe56789,Novotortsev Vladimir M.1234

Affiliation:

1. N. S. Kurnakov Institute of General and Inorganic Chemistry

2. Russian Academy of Sciences

3. 119991 Moscow

4. Russian Federation

5. CNRS

6. CRPP

7. UPR 8641

8. F-33600 Pessac

9. France

Abstract

Rare earth ferrocenoylacetonates, [Ln(fca)3(bpy)]·MeC6H5 and [Sc(fca)3]·0.5MeC6H5, were obtained, their thermolysis and magnetism were studied; the Dy complex manifests a preeminent anisotropy barrier of 241 K.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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