Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity-Reference-Cited by-同舟云学术

Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity

Published:2019 Issue:27 Volume:10 Page:6715-6720
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mitake Akihito¹²³⁴⁵,Nagai Rikako¹²³⁴⁵,Sekine Ayato¹²³⁴⁵,Takano Hideaki¹²³⁴⁵,Sugimura Natsuhiko⁶²³⁴⁵,Kanyiva Kyalo Stephen⁷²³⁴⁵^ORCID,Shibata Takanori¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. School of Advanced Science and Engineering

3. Waseda University

4. Tokyo 169-8555

5. Japan

6. Materials Characterization Central Laboratory

7. Global Center for Science and Engineering

Abstract

Silicon-tethered tetraynes with a 1,3-diyne moiety underwent consecutive hexadehydro- and tetradehydro-Diels–Alder reactions to give fused polycyclic aromatic compounds.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC00960D

Reference43 articles.

1. The Dehydro-Diels−Alder Reaction

2. Recent Progress in Dehydro(genative) Diels-Alder Reaction

3. Intramolecular [4 + 2] Cycloaddition Reactions of Diarylacetylenes: Synthesis of Benzo[b]fluorene Derivatives via Cyclic Allenes