Unexpected formation of 1,2- and 1,4-bismethoxyl Sc3N@Ih-C80 derivatives via regioselective anion addition: an unambiguous structural identification and mechanism study-Reference-Cited by-同舟云学术

Unexpected formation of 1,2- and 1,4-bismethoxyl Sc3N@Ih-C80 derivatives via regioselective anion addition: an unambiguous structural identification and mechanism study

Published:2021 Issue:23 Volume:12 Page:8123-8130
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hu Yajing¹²³⁴⁵,Yao Yang-Rong⁶⁷⁸⁹¹⁰,Liu Xuechen¹²³⁴⁵,Yu Ao¹²³⁴⁵,Xie Xiaoming⁶⁷⁸⁹¹⁰,Abella Laura¹¹¹²¹³¹⁴^ORCID,Rodríguez-Fortea Antonio¹¹¹²¹³¹⁴^ORCID,Poblet Josep M.¹¹¹²¹³¹⁴^ORCID,Akasaka Takeshi¹²³⁴⁵^ORCID,Peng Ping¹²³⁴⁵,Zhang Qianyan⁶⁷⁸⁹¹⁰,Xie Su-Yuan⁶⁷⁸⁹¹⁰,Li Fang-Fang¹²³⁴⁵^ORCID,Lu Xing¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Material Processing and Die & Mould Technology

2. School of Materials Science and Engineering

3. Huazhong University of Science and Technology

4. Wuhan

5. China

6. State Key Laboratory for Physical Chemistry of Solid Surfaces

7. Department of Chemistry

8. College of Chemistry and Chemical Engineering

9. Xiamen University

10. Xiamen 361005

11. Departament de Química Física i Inorgànica

12. Universitat Rovira i Virgili

13. 43007 Tarragona

14. Spain

Abstract

An attempt to achieve heterocyclic cycloadducts of Sc₃N@I_h-C₈₀via reaction with Ph₂CO, PhCCPh or PhCN in the presence of tetrabutylammonium hydroxide (TBAOH) stored in CH₃OH led to the formation of the unexpected bismethoxyl adducts of Sc₃N@I_h-C₈₀ (1 and 2).