A mixed-valent nonanuclear [Mn5IIMn4III] molecular cluster with cubic topology of highest symmetry as a bifunctional electrocatalyst for efficient water splitting

Author:

Sarkar Chandan1,Sarkar Tapan1,De Aditi23ORCID,Dutta Nityananda1,Kłak Julia4ORCID,Oliver Allen G.5ORCID,Tiwari Ranjay K.6,Behera J. N.6ORCID,Kundu Subrata23ORCID,Bera Manindranath1ORCID

Affiliation:

1. Department of Chemistry, University of Kalyani, Nadia, West Bengal-741235, India

2. Process Engineering (EPE) Division, Central Electrochemical Research Institute, Karaikudi-630006, Tamil Nadu, India

3. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

4. Faculty of Chemistry, University of Wroclaw, Wroclaw 50383, Poland

5. Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA

6. School of Chemical Sciences, National Institute of Science Education & Research, An OCC of Homi Bhabha National Institute, Bhubaneswar, Khurda, Odisha-752050, India

Abstract

A mixed-valent nonanuclear molecular cluster [Mn9L42-O)43-Cl)2] with cubic topology has been explored as a bifunctional electrocatalyst for efficient water splitting that produces molecular H2 and O2.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Department of Atomic Energy, Government of India

University of Kalyani

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

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