Temperature-related reaction kinetics of the vanadium(iv)/(v) redox couple in acidic solutions
Author:
Affiliation:
1. Institute of Metal Research
2. Chinese Academy of Sciences
3. Shenyang, China
Abstract
Two diffusion equations for both VO2+ and VO2+ ions in practical electrolyte (1.2 M V + 3.0 M H2SO4) have been established, which can be expressed by DVO2+ = 4 × 10−5 exp(−4240/RT) and DVO2+ = 0.18861 exp(−25 200/RT) (cm2 s−1).
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA04278F
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