Synthesis of chitin and chitosan stereoisomers by thermostable α-glucan phosphorylase-catalyzed enzymatic polymerization of α-d-glucosamine 1-phosphate

Author:

Kadokawa Jun-ichi12345,Shimohigoshi Riko12345,Yamashita Kento12345,Yamamoto Kazuya12345

Affiliation:

1. Department of Chemistry

2. Biotechnology

3. and Chemical Engineering

4. Graduate School of Science and Engineering

5. Kagoshima University

Abstract

Chitosan and chitin stereoisomers were successfully synthesized by thermostable α-glucan phosphorylase-catalyzed enzymatic polymerization of α-d-glucosamine 1-phosphate and subsequent N-acetylation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference50 articles.

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2. Cellulose: Fascinating Biopolymer and Sustainable Raw Material

3. Biodegradable polymers

4. A. Sarko and P.Zugenmaier, Crystal Structures of Amylose and Its Derivatives, in Fiber Diffraction Methods, ACS Symposium Series 141, ed. A. D. French and K. H. Gardner, American Chemical Society, Washington DC, 1980, pp. 459–482

5. Amylose-inclusion complexes: Formation, identity and physico-chemical properties

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