A cyano-bridged Cu(i)-based organic framework coupled with the C–C bond cleavage of acetonitrile for selective and sensitive sensing of Fe3+ ions
Author:
Affiliation:
1. School of Chemistry and Materials Science
2. Jiangsu Normal University
3. Xuzhou
4. P. R. China
5. State Key Lab of Structure Chemistry
6. College of Chemistry
7. Shandong Normal University
8. Jinan
Abstract
A novel cyano-bridged Cu(i)-based organic framework, in which all cyano anions were generated in situ from the C–C bond cleavage of acetonitrile, exhibits a highly selective and sensitive sensing for Fe3+ ions.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00979A
Reference64 articles.
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4. A Mechanistic Investigation of the Carbon−Carbon Bond Cleavage of Aryl and Alkyl Cyanides Using a Cationic Rh(III) Silyl Complex
5. Cleavage of Carbon−Carbon Bonds in Alkyl Cyanides Using Nickel(0)
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