A cyano-bridged Cu(i)-based organic framework coupled with the C–C bond cleavage of acetonitrile for selective and sensitive sensing of Fe3+ ions

Author:

Gai Yanli12345,Zhao Xueyan1234,Chen Yan1234,Yang Silei1234,Xia Xinshu1234,Liu Shan1234,Wan Xiuyan6784,Xiong Kecai12345ORCID

Affiliation:

1. School of Chemistry and Materials Science

2. Jiangsu Normal University

3. Xuzhou

4. P. R. China

5. State Key Lab of Structure Chemistry

6. College of Chemistry

7. Shandong Normal University

8. Jinan

Abstract

A novel cyano-bridged Cu(i)-based organic framework, in which all cyano anions were generated in situ from the C–C bond cleavage of acetonitrile, exhibits a highly selective and sensitive sensing for Fe3+ ions.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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