Kinetic analysis of overlapping multistep thermal decomposition comprising exothermic and endothermic processes: thermolysis of ammonium dinitramide

Author:

Muravyev Nikita V.1234ORCID,Koga Nobuyoshi56789ORCID,Meerov Dmitry B.1234,Pivkina Alla N.1234

Affiliation:

1. Semenov Institute of Chemical Physics

2. Russian Academy of Sciences

3. Moscow

4. Russia

5. Chemistry Laboratory

6. Department of Science Education

7. Graduate School of Education

8. Hiroshima University

9. Higashi-Hiroshima

Abstract

Multistep heterogeneous reactions with exothermic and endothermic steps are separated by an advanced kinetic analysis using simultaneous TG–DSC curves.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference66 articles.

1. N. Koga , J.Šesták and P.Šimon, in Thermal analysis of Micro, Nano- and Non-Crystalline Materials, ed. J. Šesták and P. Šimon, Springer, Netherlands, Dordrecht, 2012, vol. 9, pp. 1–28

2. Ozawa’s kinetic method for analyzing thermoanalytical curves

3. A. K. Galwey and M. E.Brown, Thermal Decomposition of Ionic Solids: Chemical Properties and Reactivities of Ionic Crystalline Phases, Elsevier, Burlington, 1999

4. Structure and order in thermal dehydrations of crystalline solids

5. A physico-geometric approach to the kinetics of solid-state reactions as exemplified by the thermal dehydration and decomposition of inorganic solids

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