1,3-Dipolar cycloaddition of nitrones to oxa(aza)bicyclic alkenes

Author:

Yao Yongqi12345,Yang Wen12345,Lin Qifu12345,Yang Weitao12345,Li Huanyong6789ORCID,Wang Lin6789,Gu Fenglong12345ORCID,Yang Dingqiao12345ORCID

Affiliation:

1. Key Laboratory of Theoretical Chemistry of Environment

2. Ministry of Education

3. School of Chemistry and Environment

4. South China Normal University

5. Guangzhou 510006

6. Analytical and Testing Center

7. Jinan University

8. Guangzhou 510632

9. People's Republic of China

Abstract

A new 1,3-dipolar cycloaddition of oxa(aza)bicyclic alkenes with nitrones has been developed without any catalyst and additive under mild conditions. The proposed concerted mechanism is investigated by DFT calculations of the reaction pathways.

Funder

National Basic Research Program of China

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Guangzhou Municipal Science and Technology Project

Guangdong Province Higher Vocational Colleges and Schools Pearl River Scholar Funded Scheme

Leading Talents Program of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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