Gate-opening upon CO2 adsorption on a metal–organic framework that mimics a natural stimuli-response system

Abstract

A dynamic d-champhorate-based protuberant-grid-type framework, undergoes gate opening and closing processes that were triggered by the stimuli of the adsorption or desorption of CO₂. It is able to specifically recognize CO₂ over than N₂ and H₂ and shows a high CO₂ uptake of 90 mg g⁻¹ under 35 bar at 298 K.