Photocatalytic function of the B12 complex with the cyclometalated iridium(iii) complex as a photosensitizer under visible light irradiation

Author:

Tian Hui12345,Shimakoshi Hisashi12345ORCID,Park Gyurim6789,Kim Sinheui6789,You Youngmin6789ORCID,Hisaeda Yoshio12345ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Graduate School of Engineering

3. Kyushu University

4. Fukuoka 819-0395

5. Japan

6. Division of Chemical Engineering and Materials Science

7. Ewha Womans University

8. Seoul 03760

9. Republic of Korea

Abstract

A visible light induced three-component catalytic system with the cobalamin derivative (B12) as a catalyst, the cyclometalated iridium(iii) complex as a photosensitizer and triethanolamine as an electron source under N2 was developed.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference44 articles.

1. Glutamate and 2-methyleneglutarate mutase: from microbial curiosities to paradigms for coenzyme B12-dependent enzymes

2. Vitamin B12 and B12-Protein , ed. B. Kraütler , D. Arigoni and B. T. Golding , Wiley-VCH , Weinheim , 1998

3. Chemistry and Biochemistry of B12 , ed. R. Banerjee , Wiley-Interscience , New York , 1999

4. The Many Faces of Vitamin B12: Catalysis by Cobalamin-Dependent Enzymes

5. Radical Catalysis in Coenzyme B12-Dependent Isomerization (Eliminating) Reactions

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