Photocatalytic function of the B12 complex with the cyclometalated iridium(iii) complex as a photosensitizer under visible light irradiation
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. Graduate School of Engineering
3. Kyushu University
4. Fukuoka 819-0395
5. Japan
6. Division of Chemical Engineering and Materials Science
7. Ewha Womans University
8. Seoul 03760
9. Republic of Korea
Abstract
A visible light induced three-component catalytic system with the cobalamin derivative (B12) as a catalyst, the cyclometalated iridium(iii) complex as a photosensitizer and triethanolamine as an electron source under N2 was developed.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT03742B
Reference44 articles.
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3. Chemistry and Biochemistry of B12 , ed. R. Banerjee , Wiley-Interscience , New York , 1999
4. The Many Faces of Vitamin B12: Catalysis by Cobalamin-Dependent Enzymes
5. Radical Catalysis in Coenzyme B12-Dependent Isomerization (Eliminating) Reactions
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