Visible-light-induced indole synthesis <i>via</i> intramolecular C–N bond formation: desulfonylative C(sp<sup>2</sup>)–H functionalization-Reference-Cited by-同舟云学术

Visible-light-induced indole synthesis via intramolecular C–N bond formation: desulfonylative C(sp²)–H functionalization

Published:2022 Issue:39 Volume:13 Page:11623-11632
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Quanzhe¹,Gu Xintao¹,Wei Yin¹,Shi Min¹²^ORCID

Affiliation:

1. State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Science, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China

2. Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China

Abstract

LED visible-light-induced redox neutral desulfonylative C(sp2)–H functionalization for the synthesis of N-substituted indoles in the absence of any additional additive has been established on the basis of KIE, Hammett plotting and DFT calculations.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02822K

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1. Divergent Strategy in Natural Product Total Synthesis

2. Sesquiterpenyl indoles