Hybrid molecular/enzymatic catalytic cascade for complete electro-oxidation of glycerol using a promiscuous NAD-dependent formate dehydrogenase from Candida boidinii-Reference-Cited by-同舟云学术

Hybrid molecular/enzymatic catalytic cascade for complete electro-oxidation of glycerol using a promiscuous NAD-dependent formate dehydrogenase from Candida boidinii

Published:2017 Issue:39 Volume:53 Page:5368-5371
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Abdellaoui Sofiene¹²³,Seow Chavez Madelaine⁴⁵⁶⁷³,Matanovic Ivana⁴⁵⁶⁷³,Stephens Andrew R.¹²³,Atanassov Plamen⁴⁵⁶⁷³,Minteer Shelley D.¹²³^ORCID

Affiliation:

1. Departments of Chemistry and Materials Science and Engineering

2. Salt Lake City

3. USA

4. The Department of Chemical and Biological Engineering

5. Center for Micro-Engineered Materials (CMEM)

6. University of New Mexico

7. Albuquerque

Abstract

The formate dehydrogenase from Candida boidinii was combined with NH₂-TEMPO to form a novel hybrid anode to oxidize glycerol to carbon dioxide at near-neutral pH.

Funder

Army Research Office

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC01027C

Reference29 articles.

1. Oxydation electrocatalitique du glycerol sur electrodes d'or et de platine en milieu aqueux

2. Electrocatalytic selective oxidation of glycerol to tartronate on Au/C anode catalysts in anion exchange membrane fuel cells with electricity cogeneration

3. Electro-oxidation of glycerol at Pd based nano-catalysts for an application in alkaline fuel cells for chemicals and energy cogeneration

4. Complete Oxidation of Glycerol in an Enzymatic Biofuel Cell

5. Kinetic and transport analysis of immobilized oxidoreductases that oxidize glycerol and its oxidation products

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