Stabilization of a bismuth–bismuth double bond by anionic N-heterocyclic carbenes
Author:
Affiliation:
1. Institut für Anorganische und Analytische Chemie
2. Technische Universität Braunschweig
3. 38106 Braunschweig
4. Germany
Abstract
Anionic N-heterocyclic carbenes have been employed for the isolation of the first dicarbene–dibismuth complex; the resulting dibismuthene features a trans-bent geometry with a Bi–Bi double bond and short intramolecular Bi–Cipso contacts.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00140J
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