The role of carbonate as a catalyst of Fenton-like reactions in AOP processes: CO3˙− as the active intermediate-Reference-Cited by-同舟云学术

The role of carbonate as a catalyst of Fenton-like reactions in AOP processes: CO3˙− as the active intermediate

Published:2014 Issue:86 Volume:50 Page:13096-13099
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Burg Ariela¹²³,Shamir Dror⁴³,Shusterman Inna⁵⁶³,Kornweitz Haya⁷⁸⁹,Meyerstein Dan⁵⁶³⁷⁸

Affiliation:

1. Chemical Engineering Department

2. SCE – Shamoon College of Engineering

3. Beer-Sheva, Israel

4. Nuclear Research Centre Negev

5. Chemistry Department

6. Ben-Gurion University of the Negev

7. Biological Chemistry Department

8. Ariel University

9. Ariel, Israel

Abstract

The reaction Co(H₂O)₆²⁺ + H₂O₂ proceeds via a transient that decomposes into Co^II(H₂O)(OOH)(OH)₂ + CO₃˙⁻. Plausible biological implications are pointed out.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC05852F

Reference41 articles.

1. Manganese-Catalyzed Epoxidations of Alkenes in Bicarbonate Solutions

2. High performance of a simple cobalt(II)–monoethanolamine complex for orange II degradation with H2O2 as an oxidant at ambient conditions

3. Formation of alkyl peroxides in oxidation of alkanes by H2O2 catalyzed by transition metal complexes

4. C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

5. Selective Degradation of Orange II with the Cobalt(II)–Bicarbonate–Hydrogen Peroxide System

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