DppfCuBH4: new reducing agents for the synthesis of ferrocene-functionalized metal nanoclusters

Author:

Wang Meng12,Li Simin1,Chen Huijun3,Sun Xueli1,Sun Jing1,Jia Yanyuan2,Guo Shuo2,Sun Cunfa4ORCID,Shen Hui1ORCID

Affiliation:

1. College of Energy Materials and Chemistry, Inner Mongolia University, Hohhot 010021, China

2. College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China

3. College of Food Science and Pharmaceutical Engineering, Wuzhou University, Guangxi, 543000, China

4. College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China

Abstract

A novel type of functional reducing agent, dppfCuBH4, has been developed. Reduction of silver complexes by the reductant affords two ferrocene-functionalized clusters of [Ag25Cu4(dppf)6(3-F-PhCC)12Cl6]3+and [Ag4(dppf)5Cl2]2+in a facile way.

Funder

Inner Mongolia University of Science and Technology

Inner Mongolia University

Natural Science Foundation of Inner Mongolia

Fundamental Research Funds for the Central Universities

Research Program of Science and Technology at Universities of Inner Mongolia Autonomous Region

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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