Controlling the sensitivity and selectivity for the detection of nitro-based explosives by modulating the electronic substituents on the ligand of AIPE-active cyclometalated iridium(<scp>iii</scp>) complexes-Reference-Cited by-同舟云学术

Controlling the sensitivity and selectivity for the detection of nitro-based explosives by modulating the electronic substituents on the ligand of AIPE-active cyclometalated iridium(iii) complexes

Published:2023 Issue:39 Volume:52 Page:14182-14193
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Agarwal Annu¹^ORCID,Bhatta Ram Prasad¹,Kachwal Vishal¹²,Laskar Inamur Rahaman¹^ORCID

Affiliation:

1. Department of Chemistry, BITS Pilani, Pilani Campus, Rajasthan, 333031, India

2. Department of Engineering Science, University of Oxford, Oxford, UK

Abstract

AIE active cyclometalated complexes of iridium(iii) exhibiting high quantum yield showed selective and sensitive detection of TNT and TNP explosives through rationally choosing the appropriate electronic substituents on the cyclometalated ligand.

Funder

Council of Scientific and Industrial Research, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02198J

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4. J.Akhavan , The Chemistry of Explosives , Royal Society of Chemistry , 2022

5. Nitrite Elimination and Hydrolytic Ring Cleavage in 2,4,6-Trinitrophenol (Picric Acid) Degradation

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1. Synthesis of two coordination polymers for fluorescence sensing of dinotefuran and 2,4,6-Trinitrophenol;Inorganica Chimica Acta;2024-11

2. AIE-active cyclometalated iridium(iii) complexes for highly efficient picric acid detection in aqueous media;Inorganic Chemistry Frontiers;2024

3. Enhanced TNT vapor sensing through a PMMA-mediated AIPE-active monocyclometalated iridium(iii) complex: a leap towards real-time monitoring;The Analyst;2024