Symmetry breaking of the bending mode of CO2 in the presence of Ar

Author:

Gartner T. A.1234,Barclay A. J.1234,McKellar A. R. W.564,Moazzen-Ahmadi N.1234ORCID

Affiliation:

1. Department of Physics and Astronomy

2. University of Calgary

3. Calgary

4. Canada

5. National Research Council of Canada

6. Ottawa

Abstract

The weak infrared spectrum of CO2–Ar corresponding to the (0111) ← (0110) hot band of CO2 is detected in the region of the carbon dioxide ν3 fundamental vibration, using a tunable OPO laser source to probe a pulsed supersonic slit jet expansion.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference27 articles.

1. Free‐jet infrared absorption spectroscopy of the C2H2–Ar complex in the doubly degenerate monomer C–H bending region

2. J. Norooz Oliaee , B.Brockelbank and N.Moazzen-Ahmadi , Use of quantum correlated twin beams for cancellation of power fluctuations in a continuous wave optical parametric oscillator for high-resolution spectroscopy in the rapid scan , The 25th Colloquium on High Resolution Molecular Spectroscopy , Helsinki , Finland , 2017 , pp. 20–25

3. Determination of the structure of ArCO2by radio frequency and microwave spectroscopy

4. Erratum: Determination of the structure of ArCO2 by radiofrequency and microwave spectroscopy [J. Chem. Phys. 70, 4095 (1979)]

5. Optothermal‐infrared and pulsed‐nozzle Fourier‐transform microwave spectroscopy of rare gas–CO2complexes

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