Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo(vi) centres of Ru(ii)

Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo(vi) centres of Ru(ii)–Mo(vi) dyads

Published:2021 Issue:34 Volume:57 Page:4142-4145
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Nazari Haghighi Pashaki Maryam¹²³⁴^ORCID,Choi Tae-Kyu⁵⁶⁷^ORCID,Rohwer Egmont J.¹²³⁴,Feurer Thomas¹²³⁴,Duhme-Klair Anne-Kathrin⁸⁹¹⁰¹¹^ORCID,Gawelda Wojciech¹²¹³¹⁴¹⁵¹⁶^ORCID,Cannizzo Andrea¹²³⁴^ORCID

Affiliation:

1. Institute of Applied Physics

2. University of Bern

3. Bern

4. Switzerland

5. European XFEL

6. 22869 Schenefeld

7. Germany

8. Department of Chemistry

9. University of York

10. Heslington

11. UK

12. Departamento de Química

13. Facultad de Ciencias

14. Universidad Autónoma de Madrid

15. 28049 Madrid

16. Spain

Abstract

Photoinduced oxidation-enhancement in Ru(ii)–Mo(vi) photocatalysts is caused by an ultrafast process where both the moieties are photoactivated.

Funder

Engineering and Physical Sciences Research Council

H2020 European Research Council

Comunidad de Madrid

Universidad Autónoma de Madrid

Ministerio de Ciencia, Innovación y Universidades

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC00750E

Reference23 articles.

1. Evolutionary history of redox metal-binding domains across the tree of life

2. Moving Protons and Electrons in Biomimetic Systems

3. Proton-Coupled Electron Flow in Protein Redox Machines

4. Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

5. Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Reactivity of metal dioxo complexes;Dalton Transactions;2024

2. Recent advances in MXenes: a promising 2D material for photocatalysis;Materials Chemistry Frontiers;2023